Name:
ASTM D7979-17 PDF
Published Date:
07/15/2017
Status:
Active
Publisher:
ASTM International
1.1 This procedure covers the determination of selected per- and polyfluoroalkyl substances (PFASs) in a water matrix using liquid chromatography (LC) and detection with tandem mass spectrometry (MS/MS). These analytes are qualitatively and quantitatively determined by this method. This method adheres to a technique known as selected reaction monitoring (SRM) or sometimes referred to as multiple reaction monitoring (MRM). This is not a drinking water method, performance of this test method has not been evaluated on drinking water matrices.
1.2 The Method Detection Limit (MDL)2 and Reporting Range3 for the target analytes are listed in Table 1. The target concentration for the reporting limit for this test method was 10 ng/L for most of the target analytes at the time of development.
AnalyteA
MDL
(ng/L)
Reporting Ranges
(ng/L)
PFTreAB
1.2
10 - 400
PFTriAB
0.7
10 - 400
PFDoAB
1.2
10 - 400
PFUnAB
1.2
10 - 400
PFDAB
1.4
10 - 400
PFOSB
2.2
10 - 400
PFNAB
1.1
10 - 400
PFecHSB
1.9
10 - 400
PFOAB
1.7
10 - 400
PFHxSB
1.2
10 - 400
PFHpAB
1.0
10 - 400
PFHxAB
2.0
10 - 400
PFBSB
0.8
10 - 400
PFPeAB
4.6
50 - 2000
PFBAB
4.6
50 - 2000
FHEA
92.9
300 - 8000
FOEA
106.8
300 - 8000
FDEA
47.2
200 - 8000
FOUEA
2.3
10 - 400
FHpPA
3.3
10 - 400
FHUEA
1.5
10 - 400
(A) Acronyms are defined in 3.3.(B) New MDL study was reported in August 2016, which resulted in a reporting limit and range update.1.2.1 The reporting limit in this test method is the minimum value below which data are documented as non-detects. The reporting limit may be lowered providing your lab meets the minimum performance requirements of this test method at the lower concentrations, this method is performance based and modifications are allowed to improve performance. Analyte detections between the method detection limit and the reporting limit are estimated concentrations and are not reported following this test method. In most cases, the reporting limit is the concentration of the Level 1 calibration standard as shown in Table 4 for the PFASs after taking into account the 50 % dilution with methanol. It is above the Level 1 calibration concentration for FHEA and FOEA, these compounds can be identified at the Level 1 concentration but the standard deviation among replicates at this lower spike level resulted in a higher reporting limit.
| File Size : | 1 file , 360 KB |
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| Number of Pages : | 27 |
| Published : | 07/15/2017 |
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