Application of Differential Thermal Analysis in Cement Chemistry PDF

Preface ix

Acknowledgments xiii

Abbreviations xv

I. Differential Thermal Analysis Technique 

II. Theory and Typical Applications 28

• II.l Theoretical Considerations 28
• II.2 Typical Applications 34

III. Formation of Portland Cement Clinker and Polymorphism of C3S and C2S 54

• III.1 Formation of Portland Cement Clinker 54
• III.2 Polymorphism of C3S 71 
• III.3 Polymorphism of C2S 75 

IV. Hydration of Portland Cement 81 

• IV.l Systems Containing CaO, AI20 a, Si02, and H20 at Ordinary Temperatures 81 
• IV.2 Hydration of Portland Cement 88

V. Hydration of Individual Phases in Portland Cement 111

• V.l Hydration of C3A 111
• V.2 Hydration of C3S and B-C2S 127
• V.3 Hydration of the Ferrite Phase 135

VI. Hydration of C3A in Presence of Salts 139

• VI.1 Hydration of C3A in Presence of Gypsum 139
• VI.2 Hydration of C3A in Presence of Lignosulfonate 155
• VI.3 Hydration of C3A in Presence of Calcium Chloride 159
• VI.4 Hydration of C3A in Presence of Calcium Carbonate 160

VII. Autoclaved Cementitious Products 165

VIII. Non-Portland Cements Based on Silicates and Aluminates 196

• VIII.1 Slags and Slag Cements 196
• VIII.2 High Alumina Cement 206
• VIII.3 Pozzolanas and Pozzolanic Cements 213
• VIII.4 Oil Well Cement 222
• VIII.5 Hydraulic Lime 223
• VIlI.6 Expanding Cement 227
• VIII.7 Acid-Proof Cement 230

IX. Other Non-Portland Cements 231

• IX.l Magnesium Oxychloride and Oxysulfate Cement 231
• IX.2 Gypsum Plaster 251
• IX.3 Sand-Lime Mortar 271
• IX.4 Phosphate Cement 275

X. Aggregates 276

Subject Index 297

Author Index 303