DANSK DSF/FPREN ISO 3251 PDF

This document specifies a method for determining the non-volatile-matter content by mass of paints, varnishes, binders for paints and varnishes, polymer dispersions and condensation resins such as phenolic resins (resols, novolak solutions etc.). The method is also applicable to formulated dispersions containing fillers, pigments and other auxiliaries (e.g. thickeners, film-forming agents). For the method to be usable for unplasticized polymer dispersions and rubber lattices, the non-volatile residue (which consists essentially of the polymeric material and of small quantities of auxiliaries such as emulsifiers, protective colloids, stabilizers, solvents added as film-forming agents and – especially for rubber latex concentrate – preserving agents) has to be chemically stable under the test conditions. For plasticized samples, the residue, by definition, normally includes the plasticizer. NOTE 1 – The non-volatile-matter content of a product is not an absolute quantity but depends upon the temperature and period of heating used for the determination. Consequently, when using this method, only relative and not true values for non-volatile-matter content are obtained owing to solvent retention, thermal decomposition and evaporation of low molecular mass constituents. The method is therefore primarily intended for testing different batches of the same type of product. NOTE 2 – This method is suitable for synthetic rubber latices provided heating for a specific period of time is considered appropriate (ISO 124 specifies heating until the loss in mass of a 2 g test portion following successive periods of heating is less than 0,5 mg). NOTE 3 – In-house methods for determining non-volatile matter often include drying with infrared or microwave radiation. Standardization of such methods is not possible, since they are not generally applicable. Several polymer compositions tend to decompose during such treatment and therefore give incorrect results. ISO 3233 (all parts) specifies test methods for determining the volume of non-volatile matter in paints, varnishes and related products.