This document specifies a method for the determination of the elements aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium, erbium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, palladium, phosphorus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, titanium, tungsten, uranium and its isotopes, vanadium, yttrium, ytterbium, zinc and zirconium in water (e.g. drinking water, surface water, ground water, waste water and eluates).
Taking into account the specific and additionally occurring interferences, these elements can be determined in water and digests of water and sludge (e.g. digests of water as described in ISO 15587-1 or ISO 15587-2).
The working range depends on the matrix and the interferences encountered. In drinking water and relatively unpolluted waters, the limit of quantification (
LOQ) lies between 0,002 μg/l and 1,0 μg/l for most elements (see Table 1). The working range typically covers concentrations between several ng/l and mg/l depending on the element and specified requirements.
The quantification limits of most elements are affected by blank contamination and depend predominantly on the laboratory air-handling facilities available on the purity of reagents and the cleanliness of glassware.
The lower limit of quantification is higher in cases where the determination suffers from interferences (see Clause 5) or memory effects (see ISO 17294-1).
Elements other than those mentioned in the scope can also be determined according to this document provided that the user of the document is able to validate the method appropriately (e.g. interferences, sensitivity, repeatability, recovery).
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| Published : | 10/01/2023 |
