ASTM D7598-09e2 PDF

ASTM D7598-09e2 PDF

Name:
ASTM D7598-09e2 PDF

Published Date:
12/01/2009

Status:
Active

Description:

Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry

Publisher:
ASTM International

Document status:
Active

Format:
Electronic (PDF)

Delivery time:
10 minutes

Delivery time (for Russian version):
200 business days

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1.1 This procedure covers the determination of thiodiglycol (TDG) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS). TDG is qualitatively and quantitatively determined by this method. This method adheres to single reaction monitoring (SRM) mass spectrometry.

1.2 This test method has been developed by US EPA Region 5 Chicago Regional Laboratory (CRL).

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 The Detection Verification Level (DVL) and Reporting Range for TDG are listed in Table 1.

TABLE 1 Detection Verification Level and Reporting Range

Analyte

DVL (μg/L)

Reporting Range (μg/L)

Thiodiglycol

20

100-10 000


1.4.1 The DVL is required to be at a concentration at least 3 times below the reporting limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratio at the DVL.

Example SRM Chromatograms Signal/Noise at Detection
 Verification Level
FIG. 1 Example SRM Chromatograms Signal/Noise at Detection Verification Level

1.4.2 The RL is the concentration of the level 1 calibration standard as shown in Table 2. The reporting limit for this method is 100 μg/L.

TABLE 2 Concentrations of Calibration Standards (PPB)

Analyte/Surrogate

LV 1

LV 2

LV 3

LV 4

LV 5

LV 6

LV 7

Thiodiglycol

100

250

500

1000

2500

5000

10 000

3,3'-Thiodipropanol

100

250

500

1000

2500

5000

10 000


1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.


File Size : 1 file , 260 KB
Note : This product is unavailable in Russia, Ukraine, Belarus
Number of Pages : 8
Published : 12/01/2009

History

ASTM D7598-16(2024)
Published Date: 04/01/2024
Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry
$18.9
ASTM D7598-16(2017)
Published Date: 06/15/2017
Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry
$22.5
ASTM D7598-09e2
Published Date: 12/01/2009
Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry
$18
ASTM D7598-09e1
Published Date: 12/01/2009
Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry
$18
ASTM D7598-09
Published Date: 12/01/2009
Standard Test Method for Determination of Thiodiglycol in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry
$17.4

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