ASTM D7600-09e1 PDF

1.1 This procedure covers the determination of aldicarb, carbofuran, oxamyl and methomyl (referred to collectively as carbamates in this test method) in surface water by direct injection using liquid chromatography (LC) and detected with tandem mass spectrometry (MS/MS). These analytes are qualitatively and quantitatively determined by this method. This method adheres to multiple reaction monitoring (MRM) mass spectrometry.

1.2 This test method has been developed by US EPA Region 5 Chicago Regional Laboratory (CRL).

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 The Detection Verification Level (DVL) and Reporting Range for the carbamates are listed in Table 1.

1.4.1 The DVL is required to be at a concentration at least 3 times below the Reporting Limit (RL) and have a signal/noise ratio greater than 3:1. Fig. 1 displays the signal/noise ratios of the primary single reaction monitoring (SRM) transitions and Fig. 2 displays the confirmatory SRM transitions at the DVLs for the carbamates.

1.4.2 The reporting limit is the concentration of the Level 1 calibration standard as shown in Table 2 for the carbamates.

1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

TABLE 1 Detection Verification Level and Reporting Range

AnalyteDVL (μg/L)Reporting Range (μg/L) Aldicarb1001-100 Carbofuran1001-100 Oxamyl1001-100 Methomyl1001-100

TABLE 2 Concentrations of Calibration Standards (PPB)

Analyte/Surrogate LV 1LV 2LV 3LV 4LV 5LV 6 Aldicarb15102550100 Carbofuran15102550100 Oxamyl15102550100 Methomyl15102550100 BDMC (Surrogate)2102050100200

FIG. 1 Example Primary SRM Chromatograms Signal/Noise Ratios

FIG. 2 Example Confirmatory SRM Chromatograms Signal/Noise Ratios

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Published :	12/01/2009